
Electrolytic capacitors use a chemical feature of some special metals, earlier called "valve metals". Applying a positive voltage to the anode material in an electrolytic bath forms an insulating oxide layer with a thickness corresponding to the applied voltage. This oxide layer acts as the dielectric in an electrolytic capacitor. The properties of this aluminum oxide layer compared with tantalum pentoxide dielectric layer are given in the following table: [pdf]
A second aluminum foil, the so-called cathode foil, serves as a large-surfaced contact area for passing current to the oper-ating electrolyte. The anode of an aluminum electrolytic capacitor is an aluminum foil of extreme purity.
The cathode foil has a capacitance (Cc) that uses the oxide layer, which formed by the forming voltage or formed naturally during storage (generally 1V or less), as a dielectric. According to the construction of aluminum electrolytic capacitors, Ca and Cc are connected in a series.
In contrast to other capacitors, the counter electrode (the cathode) of alumi-num electrolytic capacitors is a conductive liquid, the operating electrolyte. A second aluminum foil, the so-called cathode foil, serves as a large-surfaced contact area for passing current to the oper-ating electrolyte.
A 0.05~0.11 mm thick anode foil and a 0.02~0.05 mm thick cathode foil are continuously etched electrochemically in a chloride solution with an AC or DC current. This enlarges the effective surface area of the aluminum foils to attain smaller capacitor sizes. The process develops aluminum oxide (Al203) to form a capacitor dielectric.
1. General Description of Aluminum Electrolytic Capacitors An aluminum electrolytic capacitor consists of cathode aluminum foil, capacitor paper (electrolytic paper), electrolyte, and an aluminum oxide film, which acts as the dielectric, formed on the anode foil surface.
The anode of an aluminum electrolytic capacitor is an aluminum foil of extreme purity. The effec-tive surface area of this foil is greatly enlarged (by a factor of up to 200) by electrochemical etch-ing in order to achieve the maximum possible capacitance values.

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