
Material properties of intrinsic absorber have been discussed in section “Properties of Nanocrystalline Silicon.” However, nc-Si:H with high material quality (such as proper crystallinity, low defect-related absorption, appreciable photovoltaic properties) is not sufficient to ensure the high efficiency of solar cell. The additional. . A high Voc is of great importance to achieve the high conversion efficiency. The Vocis typically subjected to doped layers, the mobility gap of intrinsic layer, bulk properties of intrinsic layer, and the recombinations at p/i. . Light management is an important strategy for efficiency improvement. The light losses in nc-Si:H solar cells mainly include the following three aspects: (1) the insufficient front-side in. [pdf]
The new nanocrystalline solar cell achieves for the first time the separation of light absorption and charge carrier transport rendering its production costs at least five times lower than that of conventional silicon based devices. The production methods are very simple, and components of the cell are available at a low cost.
Until now, photovoltaics — the conversion of sunlight to electrical power — has been dominated by solid-state junction devices, often made of silicon. But this dominance is now being challenged by the emergence of a new generation of photovoltaic cells, based, for example, on nanocrystalline materials and conducting polymer films.
In addition, nanocrystalline silicon also differs from the silicon nanocrystal material that consists of small nanocrystals (typically <5 nm) demonstrating quantum effects (see Chaps. 24, “Nanocrystalline Silicon-Based Multilayers and Solar Cells” and 26, “Colloidal Silicon Quantum Dots and Solar Cells” ).
In the conventional picture, the photovoltage of photoelectrochemical cells does not exceed the potential drop in the space-charge layer (Box 1 Figure). But nanocrystalline cells can develop photovoltages close to 1 V even though the junction potential is in the millivolt range.
Conventional photovoltaic cells for solar energy conversion into electricity are solid state devices do not economically compete for base load utility electricity production. The low cost and ease of production of the new nanocrystalline cell should be benefit large scale applications in particular in underdeveloped or developing countries.
The phenomenal recent progress in fabricating and characterizing nanocrystalline materials has opened up whole new vistas of opportunity. Contrary to expectation, some of the new devices have strikingly high conversion efficiencies, which compete with those of conventional devices.
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