The electrochemical properties of Ga2Se3 thin films prepared by thermal co- evaporation technique have been investigated for the first time. The reversible discharge capacity of 700 mAh g(-1) was
Tin nitride thin films have been reported as promising negative electrode materials for lithium-ion solid-state microbatteries. However, the reaction mechanism of this material has not been
A novel all-solid-state thin-film-type rechargeable lithium-ion battery employing in situ prepared both positive and negative electrode materials is proposed. A lithium-ion conducting solid electrolyte sheet of Li 2 O–Al 2 O 3 –TiO 2 –P 2 O 5-based glass–ceramic manufactured by OHARA Inc. (OHARA sheet) was used as the solid electrolyte, which was sandwiched by Cu
In 1969, Liang et al. developed the first TFLBs of AgI/LiI/Li by spray and vacuum deposition. In 1983, Kanehori et al. reported the secondary TFLBs of TiS 2 /Li 3.6 Si 0.6 P 0.4 O 4 /Li by
Due to its high theoretical gravimetric capacity, which is close to 3579 mAh g −1 at room temperature, silicon (Si) is a promising negative electrode material for Li-ion microbatteries with high-energy density. However, the use of Si-based negative electrode is accompanied by a major problem consisting of its high volume expansion during
In order to study the microscopic morphology of the electrode before and after the silicon negative electrode cycle, the button cell was disassembled in a glove box after the electrochemical test, and the disassembled electrode was cleaned with DMC (dimethyl carbonate) to remove the residual electrolyte on the surface of the electrode, and the electrode was
Thin-film lithium-ion batteries are the most competitive power sources for various kinds of micro-electro-mechanical systems and have been extensively researched. The present paper reviews the recent progress on Sn-based thin-film anode materials, with particular emphasis on the preparation and performances of pure Sn, Sn-based alloy, and Sn-based
Thin-film batteries are solid-state batteries comprising the anode, the cathode, the electrolyte and the separator. They are nano-millimeter-sized batteries made of
A systematic study on the sputtered Mo 2 N thin film electrodes deposited with various growth temperatures, percentages of N 2 gas flow, and deposition times for the application of charge storage has been done by Chen et al. [97] There is a large amount of amorphous Mo in the Mo 2 N thin film electrode as the growth temperature is lower than 300
The thin-film lithium-ion battery is a form of solid-state battery. [1] Its development is motivated by the prospect of combining the advantages of solid-state batteries with the advantages of thin-film manufacturing processes.. Thin-film construction could lead to improvements in specific energy, energy density, and power density on top of the gains from using a solid electrolyte.
Conclusions Tin nitride is a very promising negative electrode material for thin-film battery applications, showing very high volumetric capacity 共700 Ah cm−2 m−1兲 and good cycle life when cycled in a liquid electrolyte. Moreover, films of composition 1:1 present better capacity retention than those of composition 3:4.
The present paper reviews the recent progress on Sn-based thin-film anode materials, with particular emphasis on the preparation and performances of pure Sn, Sn-based
The electrochemical performance, structure, composition and morphology of Ga 2 Se 3 thin film were characterized by galvanostatic cycling, cyclic voltammetry (CV), High
Abstract Among high-capacity materials for the negative electrode of a lithium-ion battery, Sn stands out due to a high theoretical specific capacity of 994 mA h/g and the presence of a low-potential discharge plateau. However, a significant increase in volume during the intercalation of lithium into tin leads to degradation and a serious decrease in capacity. An
The structure of thin films prepared by magnetron sputtering has been studied by Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX) analysis, X-ray
Metallic alloy/composite negative electrode materials are the subject of intense research. 1–27 Si- and Sn-based negative electrodes often contain elements with a lower (e.g., C, Al, Sb, Ag) or negligible (e.g., transition and rare-earth metals) capacity for Li that can improve the overall performance of the electrode by improving the conductivity, reducing the overall
The transition metal nitride (TMN) thin films used as the electrodes for lithium-ion batteries (LIBs) and supercapacitors (SCs) have been completely reviewed and
For ASSTFBs, thermally evaporated Li thin film or sputtered Si thin film was used as the RE and counter electrode to replace the Li foil. For liquid cells, the same thickness of LFP electrodes was used as WE and pure Li foils as counter electrodes. One piece of polypropylene separator was used in each cell.
A thin film battery is fabricated on an alumina substrate by RF magnetron sputtering method. Each component of battery was deposited in the sequence of a Pt current collector, a LiCoO 2 positive electrode, a Li 1.9 Si 0.28 P 1.0 O 1.1 N 1.0 electrolyte, a Si–V negative electrode, a V buffer layer, and a Cu current collector. The deposition parameters for
Download Citation | Study of silicon (and germanium) thin films as negative electrode for lithium-ion (micro)battery | Silicon which has a theoretical capacity of 3579 mAh.g-1 and low insertion
The solid-state thin-film μ-battery belongs to the family of ASSB but in a small format. There are vast choices for the positive electrode while there are much less possible
DOI: 10.1016/S1388-2481(02)00528-3 Corpus ID: 98366962; An all-solid-state thin film battery using LISIPON electrolyte and Si–V negative electrode films @article{Lee2003AnAT, title={An all-solid-state thin film battery using LISIPON electrolyte and Si–V negative electrode films}, author={Seung-Joo Lee and Hong Koo Baik and Sung-man Lee}, journal={Electrochemistry
The iron-containing electrode material is a promising candidate for low-cost Na-ion batteries. In this work, the electrochemical properties of Fe 3 O 4 nanoparticles obtained by simple hydrothermal reaction are investigated as an anode material for Na-ion batteries. The Fe 3 O 4 with alginate binder delivers a reversible capacity of 248 mAh g −1 after 50 cycles at
(a) Cycle performance of a-Si thin film when fixed charge quantity (1300, 3200, 4200 mAh/g) was inserted and extracted until the potential reaches 3 V versus Li electrode and (b) cycle life of a-Si thin film according to various cycled fixed charge quantity.
Thin film libraries of sputtered SixM1-x (M = Cr + Ni, Fe, Mn) have been investigated for use as negative electrode materials in Li-ion rechargeable batteries.
For the negative electrode, we have synthesized and screened different tin and phosphorus-based graphene materials based on the chemical structure, morphology and particle size, selecting a...
An application of thin film of silicon on copper foil to the negative electrode in lithium-ion batteries is an option. 10–12 However, the weight and volume ratios of copper to silicon become larger, and consequently a high
Yang et al. fabricated diamond-like carbon thin film and used it as an air electrode in a Li-air battery for the first time. It exhibited high discharge plateaus around 2.7 V, and large reversible-capacity around 2318 mAh g −1 at a current density of 220 mA g −1 with a capacity loss less than 1.6% per cycle for the first ten cycles.
This review summarizes the research on, and progress in such nanostructured thin-film electrode materials for lithium storage and for all-solid-state thin film batteries. Nanostructured thin film electrodes with various electrochemical reaction mechanisms based on nanometer-size effects, chemical composition and structure are summarized.
Other metal thin-films Germanium is a promising negative electrode for thin film lithium batteries due to its high theoretical capacity (1625 mAh g −1) based on the equilibrium lithium-saturated germanium phase Li 22 Ge 5. Germanium thin film showed stable capacities of 1400 mAh g −1 with 60% capacity retention after 50 cycles.
LiMO-type materials (in which M represents various metals), mainly containing layered structures and spinel structures, are the most widely used electrode materials for lithium ion batteries. Layered LiCoO 2 was the first commercialized cathode material.
J Electrochem Soc, 2006, 153: A1038–A1042 Ui K, Kikuchi S, Kadoma Y, et al. Electrochemical characteristics of Sn film prepared by pulse electrodeposition method as negative electrode for lithium secondary batteries. J Power Sources, 2009, 189: 224–229
Reproduced from Ref. . Besides their use in lithium ion batteries, carbon thin films were also utilized in lithium air batteries. Yang et al. fabricated diamond-like carbon thin film and used it as an air electrode in a Li-air battery for the first time.
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